Publication

Pyridine-induced Dimensionality Change in Hybrid Perovskite Nanocrystals

Pyridine-induced Dimensionality Change in Hybrid Perovskite Nanocrystals
Ghada H. Ahmed, Jun Yin, Riya Bose, Lutfan Sinatra, Erkki Alarousu, Emre Yengel, Noktan M. Alyami, Makhsud I. Saidaminov, Yuhai Zhang, Mohamed N. Hedhili, Osman M. Bakr, Jean-Luc Bredas, Omar F. Mohammed
Chem. Mater., 201729 (10), pp 4393–4400​
Ghada H. Ahmed, Jun Yin, Riya Bose, Lutfan Sinatra, Erkki Alarousu, Emre Yengel, Noktan M. Alyami, Makhsud I. Saidaminov, Yuhai Zhang, Mohamed N. Hedhili, Osman M. Bakr, Jean-Luc Bredas, Omar F. Mohammed
nanocrystal growth, pyridine, DFT, nanostructure, optoelectronic
2017













Engineering the surface energy through careful manipulation of the surface chemistry is a convenient approach to control quantum confinement and structure dimensionality during nanocrystal growth. Here, we demonstrate that the introduction of pyridine during the synthesis of methylammonium lead bromide (MAPbBr3) perovskites nano-crystals can transform three-dimensional (3D) cubes into two-dimensional (2D) nanostructures. Density functional theory (DFT) calculations show that pyridine preferentially binds to Pb atoms terminating the surface, driving the selective 2D growth of the nanostructures. These 2D nanostructures exhibit strong quantum confinement effects, high photoluminescence quantum yields in the visible spectral range, and efficient charge transfer to molecular acceptors. These qualities indicate the suitability of the synthesized 2D nanostructures for a wide range of optoelectronic applications. 
DOI: 10.1021/acs.chemmater.7b00872